Electrode calibration, Redox/orp electrode user guide – Thermo Products REDOX/ORP 9678BNWP User Manual

Page 8

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Redox/ORP Electrode User Guide

Electrode Calibration

ORP readings can be reported using the absolute mV values
or the E

H

mV values. E

H

mV values give the corresponding

mV values that would be obtained using a Standard Hydrogen
Electrode (SHE), also known as the Normal Hydrogen Electrode
(NHE). Orion ORP standard, Cat. No. 967901 or 967961, allows
operators to correlate measurements to the E

H

mV value with

an Orion ORP electrode.

The relative mV mode can be used to calibrate the ORP
electrode so the electrode reads the E

H

mV values in samples.

When an ORP electrode is calibrated to read E

H

mV values, the

resulting sample readings can be compared among multiple
meter and electrode systems.

Note:

If the meter can perform an automatic ORP calibration

using an E

H

mode, refer to the meter user guide for detailed

instructions on the meter calibration procedure.

1. Set the meter to the relative millivolt mode. Refer to the

meter user guide for detailed instructions.

2. Place the ORP electrode in ORP standard, Cat. No. 967901

or 967961.

3. Set the meter to the E

H

mV value of the ORP standard at

the measured temperature using the information in Table 1.

Table 1– ORP Standard Values
Absolute mV values may vary by ± 60 mV

Temperature
(°C)

E

H

Value

(mV)

Absolute Value
with Cat. No.
900011 Filling
Solution (mV)

Absolute Value
with Cat. No.
900001 Filling
Solution (mV)

0

438

218

176

1

437

218

176

2

437

218

176

3

436

218

176

4

435

218

176

5

435

218

176

6

434

218

176

7

433

218

176

8

433

218

175

9

432

219

175

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