18 metrohm co2 suppressor (mcs), 1 general information on the mcs, 2 connecting mcs – Metrohm 850 Professional IC Anion MCS Prep 2 User Manual

Page 68: 18 metrohm co, Suppressor (mcs), General information on the mcs, Connecting mcs, Figure 32, Mcs – connection, See chapter 2.18

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2.18 Metrohm CO

2

suppressor (MCS)

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58

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850 Professional IC – Anion – MCS – Prep 2

2.18

Metrohm CO

2

suppressor (MCS)

2.18.1

General information on the MCS

The MCS removes the CO

2

from the eluent flow. This reduces the back-

ground conductivity, improves the detection sensitivity and minimizes the
injection and carbonate peaks.

The MCS is used for removing CO

2

from the eluent flow before detection.

CO

2

can reach the eluent flow through the sample itself or arise through

the suppression reaction in the MSM.

The CO

2

peak is effectively minimized through connection of the MCS

between the MSM and detector. The principle is based on the gas perme-
ability of the fluoropolymer membrane inside the degassing cell of the
MCS. The eluent is guided through a capillary with a fluoropolymer mem-
brane inside the degassing cell. A vacuum is generated in the degassing
cell via a pump. At the same time, the pump sucks CO

2

-free air (CO

2

is

removed by a CO

2

adsorption cartridge (33-4)) through the degassing cell.

The pressure and concentration difference in the degassing cell in compar-
ison to the inside of the capillary now causes the CO

2

to diffuse out of the

eluent flow.

2.18.2

Connecting MCS

The MCS is connected between the MSM (see Chapter 2.16, page 50)
and detector.

1

2

3

4

4

5

5

6

7

Figure 32

MCS – connection

1

MCS input
Connection to the MSM.

2

MCS output
Connection to the detector.

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