Pontiac 1999 Firebird - Manual (Page 228)

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How to Add Coolant to the Radiator
(3800 V6 Engine)
NOTICE:
Your engine has a specific radiator fill procedure.
Failure to follow this procedure could cause your
engine to overheat and be severely damaged.
1. You can remove the radiator pressure cap when the
cooling system, including the radiator pressure cap and
upper radiator hose, is no longer hot. Turn the pressure
cap slowly counterclockwise until it first stops. (Don’t
press down while turning the pressure cap.)
If you hear a hiss, wait for that to stop. A hiss means
there is still some pressure left.