Pontiac 2005 Bonneville - Manual (Page 303)

If the overheat warning continues, there is one more
thing you can try. You can add the proper coolant
mixture directly to the radiator, but be sure the cooling
system is cool before you do it.
{ CAUTION:
Steam and scalding liquids from a hot cooling
system can blow out and burn you badly.
They are under pressure, and if you turn the
radiator pressure cap — even a little — they
can come out at high speed. Never turn the
cap when the cooling system, including the
radiator pressure cap, is hot. Wait for the
cooling system and radiator pressure cap to
cool if you ever have to turn the pressure cap.
How to Add Coolant to the Radiator
1. You can remove the radiator pressure cap when
the cooling system, including the radiator pressure
cap and upper radiator hose, is no longer hot.
Turn the pressure cap slowly counterclockwise until
it first stops. Do not press down while turning the
pressure cap.
If you hear a hiss, wait for that to stop. A hiss
means there is still some pressure left.
2. Then keep turning the pressure cap, but now push
down as you turn it. Remove the pressure cap.
5-43