Teledyne Refrigerated Sampler 6712FR - Manual (Page 214)

6712FR Refrigerated Sampler
Appendix C General Safety Procedures
C-8
Gas Chemical
Formula Common
Properties Specific
Gravity or
Vapor
Density
Air = 1 Physiological
Effect* Max
Safe
60 Min.
Exposure
ppm
Max.
Safe
8 Hour
Exposure
ppm
Explosive Range
(% by vol.
in air.)
Limits
lower/upper Likely
Location
of
Highest
Concentration Most
Common
Sources Simplest and
Cheapest
Safe Method
of Testing
Hydro-
gen Sul-
fide H
2
S Irritant and poi-
sonous volatile
compound. Rot-
ten egg odor in
small concentra-
tions. Exposure
for 2 to 15 min. at
0.01% impairs
sense of smell.
Odor not evident
at high concen-
trations. Color-
less. Flammable. 1.19 Impairs sense
of smell, rap-
idly as concen-
tration
increases.
Death in few
minutes at
0.2%. Exposure
to 0.07 to 0.1%
rapidly causes
acute poison-
ing. Paralyzes
respiratory
center. 200
to
300
20 4.3
45.0
Near bottom,
but may be
above bottom if
air is heated and
highly humid. Coal gas,
petro-
leum,
sewer gas.
Fumes
from blast-
ing under
some con-
ditions.
Sludge gas. 1. H
2
S
Ampoule.
2. 5% by weight
lead acetate
solution.
Methane CH
4
Simple asphyx-
iant.
Colorless, odor-
less, tasteless,
flammable. 0.55 Acts mechani-
cally to deprive
tissues of oxy-
gen. Does not
support life. Probably no
limit, pro-
vided oxygen
percent-age
is sufficient
for life. — 5.0 15.0 At top, increas-
ing to certain
depth. Natural
gas, sludge
gas, manu-
factured
gas, sewer
gas. Strata
of sedi-
mentary
origin. In
swamps or
marshes. 1. Combustible
gas indicator
2. Oxygen defi-
ciency indica-
tor.
Nitrogen N
2
Simple asphyx-
iant. Colorless,
tasteless.
Non-flammable.
Principal constit-
uent of air. (about
79%). 0.97 Physiologically
inert. — — — — Near top, but
may be found
near bottom. Sewer gas.
sludge gas.
Also issues
from some
rock strata. Oxygen
deficiency
indicator.
Nitrogen
Oxides NO
N 2 O
NO
2
Colorless
Colorless,
sweet odor.
Reddish-brown.
Irritating odor.
Deadly poison
1.04
1.53
1.58
60 to 150 ppm
cause irritation
and coughing.
Asphyxiant.
100 ppm dan-
gerous.
200 ppm fatal.
50 10 — — Near bottom. Industrial
wastes.
Common
air pollut-
ant. NO
2
detector
tube.
Oxygen O 2 Colorless, odor-
less, tasteless.
Supports com-
bustion. 1.11 Normal air con-
tains 20.8% of
O
2
. Man can tol-
erate down to
12%. Minimum
safe 8 hour
exposure, 14 to
16%. Below 10%,
dangerous to
life. Below 5 to
7% probably
fatal.
— — — — Variable at dif-
ferent levels. Oxygen
depletion
from poor
ventila-
tion and
absorp-
tion, or
chemical
consump-
tion of
oxygen. Oxygen defi-
ciency indica-
tor.
Ozone O
3
Irritant and poi-
sonous. Strong
electrical odor.
Strong oxidizer.
Colorless. At 1
ppm, strong sul-
fur-like odor. 1.66 Max. naturally
occurring level
is 0.04 ppm.
0.05 ppm
causes irrita-
tion of eyes and
nose. 1 to 10
ppm causes
headache, nau-
sea; can cause
coma. Symp-
toms similar to
radiation dam-
age. 0.08 0.04 — — Near bottom. Where
ozone is
used for
disinfec-
tion. Detectable
odor
at 0.015 ppm.
Table C-1 Hazardous Gases (Continued)
Gas
Chemical
Formula Common
Properties
Specific
Gravity
or Vapor
Density
Air =1
Physiological
Effect
Max
Safe 60
Min.
Exposure
ppm
Max. Safe
8 Hour
Exposure
ppm
Explosive
Range (% by
vol. in air)
Limits
lower/upper Likely
Location
of
Highest
Concentration
Most
Common
Sources
Simplest and
Cheapest
Safe Method
of Testing