Calculations, Sample calculation – VICI 230 Dynacalibrator User Manual

Page 16

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Calculations

Concentration of the permeant compound in the span outlet stream is inversely
proportional to the carrier flow rate through the chamber. It is determined using
the following equation:

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Where:

K = 24.45 / molecular weight of gas

P = permeation rate in ng/min (information included with

the permeation device documentation)

F = Chamber carrier flow (ml/min)

If the permeation rate is known for some reference temperature, the rate at a
second temperature can be estimated as follows:

log P = log P

O

+ 0.034 (T - T

O

)

Where:

P

O

= Permeation rate at reference temperature T

O

P = New permeation rate at temperature T

Certified devices should be used only at the temperature
specified on the certificate.

Using any permeation device beyond its recommended tem-
perature range could result in the destruction of the device
by explosion and/or changes in the membrane characteris-
tics. If in doubt, contact VICI Metronics with the part number
of the device to determine its maximum temperature limit.

Sample Calculation

Given:
Permeation rate: 21,000 ng/min Cl

2

@ 30°C

Carrier flow: 500 ml/min

Then:

Concentration (ppm) = K * P

F

(0.346)(21,000)

500

=

14.5

ppm

=

For zero reference measurement, remove the permeation device from the
chamber.

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