TOYOTA 2011 Sienna - Manual (Page 778)

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5-2. Steps to take in an emergency
1AR-FE engine
2GR-FE engine
Positive (+) battery terminal on your vehicle
Positive (+) battery terminal on the second vehicle
Negative (-) battery terminal on the second vehicle
Connect the clamp at the other end of the negative cable to a
solid, stationary, unpainted metallic point away from the battery
and any moving parts, as shown in the illustration.