Titration theory – Hanna Instruments HI 903 User Manual

Page 213

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21

TITRATION THEORY

5

CALCULATIONS

5.1 Equations Used in Volumetric Karl Fischer Titrations

5.1.1 Calculation of water content as % mass from samples measured by mass

C sample

Concentration of Sample (% w/w)

V titrant

Volume of Titrant (mL)

Titer

Titrant Titer (mg/mL)

m sample

Mass of Sample (g)

5.1.2 Calculation of water content as % mass from samples measured by volume

C sample

Concentration of Sample (% w/w)

V titrant

Volume of Titrant (mL)

Titer

Titrant Titer (mg/mL)

V sample

Volume of Sample (mL)

d sample

Density of Sample (g/mL)

5.1.3 Calculation of water content as % volume from samples measured by

volume

C sample

Concentration of Sample (% v/v)

V titrant

Volume of Titrant (mL)

Titer

Titrant Titer (mg/mL)

V sample

Volume of Sample (mL)

d water

Density of Water at Analysis Temperature (g/mL)

5.1.4 Calculation of water content as % mass subtracting Background Drift

Rate

C sample

Concentration of Sample (% w/w)

V titrant

Volume of Titrant (mL)

Titer

Titrant Titer (mg/mL)

Drift

Background Drift Rate (µg/min)

t

Titration Duration (min)

m sample

Mass of Sample (g)

 

   







 

 

    





    





 

 

   

  







 

 

   

  







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