Ammonia – Viking Pump TSM420: HL-LL 4925 User Manual

Page 16

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SECTION TSM 420

ISSUE

E

PAGE 16 OF 18

TABLE 1

* (Number of Btu’s to change one pound liquid ammonia

from liquid to gas)

B. Setting too high - reduce setting or get lighter

spring

C. Valve poppet binding - remove poppet, check for

burrs or foreign material

D. Shut-off valve in relief valve return line closed open

valve (would apply only to pumps with return-to-tank

type relief valves)

Ammonia (Anhydrous Ammonia, NH3)
Ammonia is a colorless gas or liquid, has a pungent odor, as

a gas is lighter than air, is easily liquefied by pressure alone

and is very soluble in water or alcohol
Ammonia is one of the best known and widely used

refrigerants in use today in ice plants, food lockers, cold

storage warehouses and other industrial cooling processes

Ammonia has a higher refrigeration effect, per unit of liquid

volume, than any other type of commonly used refrigerant;

other advantages are low initial cost and low pipe friction

losses

Ammonia, like LP-Gas and other vapor high pressure liquids,

has to be kept in a closed container to keep it from boiling

away For a given temperature the pressure built up within

the container is equal to the vapor pressure or saturation

pressure Conversely for any given pressure there is a

temperature at which the liquid and vapor are in equilibrium

(saturation temperature);

see table 1. If the pressure in

the container is held constant and the vapor is withdrawn,

the ammonia will vaporize (boil) As it boils it picks up heat

from the area around the container since over 500 Btu’s

are necessary to change one pound of ammonia from liquid

to vapor If the pressure over the ammonia is reduced, the

boiling temperature will be reduced, the boiling temperature

will be lowered

grades of Ammonia Available - commercial grade 99 5%,

refrigeration grade 99 95%
Explosive Limit in Air, by Volume - 16 0 to 25%
Corrosion - Ammonia will not attack iron or steel ever in the

presence of moisture; it will attack copper, brass, bronze and

zinc in the presence of moisture
Toxicity - Concentrations of ammonia in air as low as 53

parts per million can be detected by the sharp penetrating

odor
Exposure to ammonia causes intense irritation to the surface

tissues of the eyes, nose, throat and lungs Exposure to high

concentration of ammonia may blind, burn, strangle or kill
The effect of ammonia on the skin is that of a caustic burn,

varying in severity with the concentration of ammonia and

the length of time exposed Changes in respiratory and heart

action produced as reflex actions resulting from the irritation

of the respiratory tract
For information on the safe handling of ammonia,

see SAfE

PRACTICES, page 5.

AMMONIA

PHYSICAL PROPERTIES

Boiling point (atmospheric pressure)
Freezing point (atmospheric pressure)
Viscosity at -28°F
Specified Gravity at -28°F
Liquid Density at -28°F
Liquid Density at -28°F
* Latent heat of vaporization at -28°F

-28°F
-107 9°F
0 27 centipose
0 68
42 6 lbs /gal
5 7 lbs /gal
589 BTU

SATURATED VAPOR PRESSURE

Temp

°F

“Hg

Vacuum

PSI

Gage

PSI

Absolute

-100

180

27 4

24 3

1 24

2 74

-60

-50

18 6

14 3

5 55

7 67

-40

-30

8 7

1 6

10 4

13 9

-28

-20

0

0

3 6

14 7

18 3

-10

0

9 0

15 7

23 7

30 4

10

20

23 8

33 5

38 5

48 2

30

40

45 0

58 6

59 7

73 3

50

60

74 5

92 9

89 2

108

80

100

138

197

153

212

7. MECHANICAL SEAL LEAK.

A. Normal wear - replace seal
B. Improper installation - review installation procedure

outlined on pages 11 and 12

C. Abrasive material in liquid - if abrasive material on

ammonia side, use traps or strainer to clean system;

if on oil side, change oil more frequently and use

clean oil

D. Pump operating at very low temperature causing oil

to become heavy - use lighter oil, use immersion

heater to heat oil or consider a packed pump

Thus the temperature around the container can be controlled

by the pressure maintained in the container

Table 2 shows

the ammonia vapor pressure for various temperatures
* The same phenomena takes place to lower the boiling point

of water when the pressure is lowered This explains the low

boiling point of water on a mountain top
The saturation properties of ammonia make it desirable for

use as a refrigerant The temperatures necessary for freezing

and keeping food products can be quiet easily achieved

with pressures or vacuums readily developed by available

equipment

AMMONIA VAPOR PRESSURE

TABLE 2

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