Partial pressure of water vapor (p, Relative humidity (rh) – Vaisala DM500 User Manual

Page 131

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Appendix A __________________________________________________________ Humidity Theory

VAISALA ______________________________________________________________________ 129

Partial Pressure of Water Vapor (P

w

)

Partial pressure of water vapor refers to the part of the overall pressure
exerted by the water vapor component of a gas. Note that the partial
pressure of water vapor can be calculated when the dewpoint
temperature of a gas is known.

))

/(

(

10

n

d

d

T

T

T

m

A

Pw

+

=

(2)

Likewise, dewpoint temperature can be calculated for a given partial
pressure of water vapor.

1)

-

)

/

(

log

/

/(

10

A

P

m

T

T

w

n

d

=

(3)

where T

d

is a dewpoint temperature T

n

, m and A are constants and

their value depend on the temperature range as follows:

over water

A

m

Tn

0...60 ºC

6.1078

7.5

237.3

-20...50 ºC

6.1162

7.5892

240.71

-70...0 °C (over ice)

6.1134

9.7911

273.47

0.0001

0.001

0.01

0.1

1

10

100

1000

-80 -70 -60 -50 -40 -30 -20 -10

0

10

20

30

40

50

60

T d ,T f / °C

Pw / hPa

over water
over ice

Figure 25

Partial Pressure of Water Vapor Over Water and
Ice

Relative Humidity (RH)

Relative humidity (RH) is the ratio of the amount of water vapor
actually in the air compared to the maximum amount the can be mixed

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