LaMotte SMART Spectro Spectrophotometer - Manual (Page 152)

IRON
BIPYRIDYL METHOD • CODE 3648-SC
QUANTITY CONTENTS CODE
30 mL * Iron Reagent #1 *4450-G
5 g * Iron Reagent #2 Powder *V-4451-C
1 Pipet, 0.5 mL, plastic 0353
1 Spoon, 0.1 g, plastic 0699
*WARNING: Reagents marked with a * are considered to be potential health hazards. To view
or print a Material Safety Data Sheet (MSDS) for these reagents see MSDS CD or
www.lamotte.com. To obtain a printed copy, contact LaMotte by e-mail, phone or fax.
Most natural waters contain some iron. Its presence may vary from small traces
to very large amounts in water which is contaminated by acid mine wastes. For
domestic use, the concentration should not exceed 0.2 ppm and for some
industrial applications not even a trace of iron can be tolerated. There are
many means available for removing or reducing the iron content. Water
softening resins are effective for removing small amounts of iron and special
ion exchange materials are selective for iron removal. High concentrations of
iron can be removed by such chemical processes as oxidation and lime or
lime-soda softening. Because of the many means of removing or reducing the
amount of iron in water, the particular method employed will depend largely
on the form of iron which is present and the end use of the treated water.
APPLICATION: Drinking, surface, and saline waters; domestic and industrial
wastes.
RANGE: 0.00–6.00 Iron
METHOD: Ferric iron is reduced to ferrous iron and subsequently forms
a colored complex with bipyridyl for a quantitative measure
of total iron.
SAMPLE
HANDLING &
PRESERVATION: The sample container should be cleaned with acid and rinsed
with deionized water. Addition of acid to adjust the sample
to pH 2–3 will prevent deposition of iron on the container
walls. Samples should be analyzed as soon as possible.
INTERFERENCES: Strong oxidizing agents interfere, as well as copper and
cobalt in excess of 5.0 mg/L.
SMART SPECTRO TEST PROCEDURES 05.04 Iron–Bipyridyl Method 1/2