3 photoacoustic detection – Quantum Instruments Cascade Laser Starter Kit User Manual

Page 55

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Starter Kit Instruction Manual

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54

9.1.3

Photoacoustic detection

In the photoacoustic detection, the optical beam is
periodically modulated in amplitude before illumi-
nating the cell containing the absorbing chemical.
The expansion generated by the periodic heating
of the chemical creates an acoustic wave which is
detected by a microphone.

The two very important advantages of photoa-

coustic detection are:

• a signal is detected only in the presence of

absorption from the molecule;

• no mid-IR detectors are needed.

For these reasons, photoacoustic detection has

the potential of being cheap and very sensitive. How-
ever, ultimate sensitivity is usually limited by the
optical power of the source.

QC Laser

Chemical Cell

Microphone

w

Detection of the
acoustic wave at

w

a.c. modulation of
the laser amplitude

Fig.53: Photoacoustic technique

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