App.3-9, Ntemperature compensation error, Ncalibration solutions for conductivity – Yokogawa 2-Wire Dual Channel Transmitter/Analyzer FLXA21 User Manual

Page 237: App. isc

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<Appendix 3 For ISC (Inductive Conductivity)>

App.3-9

IM 12A01A02-01E

5th Edition : Oct. 31, 2013-00

n

Temperature compensation error

The temperature compensation error (alarm) is issued in any of the following cases.

l

TC

The error is issued when:
(measured temperature – reference temperature) < –90/compensation coefficient
The default of the temperature compensation coefficient is 2.10%/°C.
For example, when the reference temperature is 25°C, the temperature compensation coefficient

is 2.10%/°C and the measured temperature is lower than –17.9°C, the error will be issued.
Temperature compensation is performed even while an alarm is being issued.

l

Matrix

The error is issued when the temperature or the precompensated conductivity is out of the range

of the temperature compensation matrix.
In this case, however, the temperature compensation is performed by extrapolation even while

an alarm is being issued.

l

All

When the conductivity is around zero, the temperature compensation error may be issued. In this

case, the temperature compensation is not performed, and the precompensated conductivity is

displayed.
Whether the conductivity is around zero or not is determined by the temperature and conductivity

of solutions. For example, when the temperature is 20°C and the conductivity is lower than 0.033

μS/cm, the conductivity is determined to be around zero.
When measuring the conductivity around zero in air calibration or when the conductivity to be

measured is around zero, an alarm may be issued.

NOTE

To display the precompensated conductivity, set the Method to “None”.
Select Measurement setup → Temp. compensation.

n

Calibration solutions for conductivity

The calibration (cell constant) of a sensor does not change unless the sensor is damaged.
It can also appear to change because of coating of the electrodes, or partial blockage.
It does not make sense to regularly recalibrate the FLXA21.

A calibration check, however, is another matter. When the objective is clearly defined as a

diagnostic exercise a regular check can bring an extra level of security and confidence to the

measurement.
Sensor damage, and/or coatings can be difficult to see and the calibration check can confirm

their presence, by a deviation from the known solution conductivity. The remedial action should

be to clean the sensor, and carefully check for blockage or damage (not simply to recalibrate).
Higher conductivity solutions should be used where possible. The lower the conductivity of the

test solution, the easier it is to contaminate. Carbon dioxide from the air can be quickly absorbed

to cause an error. All containers must be suitably clean, and all materials suitably pure. Outside of

a well-equipped laboratory these conditions are hard to meet.

App.

ISC

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