5 calibration parameters, Calibration parameters – Metrohm 781 pH/Ion Meter User Manual

Page 85

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6 Methods / Parameters

780/781 pH/Ion Meter, Manual

75

)

old

(

value

Measured

size

.

smpl

V

factor

)

new

(

value

Measured

total

=

Please note that the unit of the measured value is not altered in this cal-

culation. The Meas. value(new) will therefore always have the same unit

as Meas. value (old), i.e. the unit which has been set under

PARAMETER

CONC/ion parameters

and with which the calibration has been carried

out.
For example, if you use the

smpl.size unit: mL

, then the quotient

V

total

/smpl.size will represent the dilution of the sample when it is larger

than one. It can also describe the concentration of a sample if it is

smaller then one.
You can also weight out your liquid sample before dilution and then se-

lect the sample size unit g. For a correct calculation the density of the

sample in g/mL should be entered as the factor.
For a more individual input of the sample data you can also have the

program automatically request the sample size and sample size unit di-

rectly before each measurement (see Preselections, Section 6.5.9 and

Section 6.6.2).

6.5.5

Calibration parameters

(applies only for measurement type: direct)

PARAMETER Conc

:

calibration parameters

: ├

temperature*

drift

report

cal.interval

no.of standards

addition

manual

-

conc.1...n

auto

min.conc.

max.conc.

V init

no.of Exchange Units

conc.1...n

V Exchange Unit 1...n

(* only appears if no temperature sensor is connected)
In the direct measurement of the concentration the calibration parame-

ters primarily describe the exact presentation of the calibration stand-

ards. The evaluation of the calibration is described in Section 9.2.2.

temperature

0.0...25.0...99.9 °C

Just as for the measuring temperature, the calibration temperature

should be entered if no temperature sensor is connected. If the measur-

ing and calibration temperatures are different then this is absolutely

necessary for the automatic temperature correction of the electrode

slope. The temperature is then stored and indicated by the suffix '

man-

ual

' in the report header.

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